REMA TIP TOP/NORTH AMERICA INC -- SPECIAL CEMENT BL-G -- -
===================== Product Identification ===================== Product ID:SPECIAL CEMENT BL-G MSDS Date:01/03/1998 FSC:NIIN:Submitter:F BT Status Code:A === Responsible Party === Company Name:REMA TIP TOP/NORTH AMERICA INC Address:200 PARIS AVE City:NORTHVALE State:NJ ZIP:07647-5000 Country:US Info Phone Num:800-334-7362/800-225-7362 Emergency Phone Num:800-334-7362 CAGE:GO624 === Contractor Identification === Company Name:REMA TIP TOP/NORTH AMERICA INC Address:200 PARIS AVE City:NORTHVALE State:NJ ZIP:07647-5000 Country:US Phone:800-334-7362/800-225-7362 CAGE:GO624 ============= Composition/Information on Ingredients ============= Ingred Name:TRICHLOROETHYLENE CAS:79-01-6 RTECS #:KX4550000 = Wt:80. OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:YES Health Hazards Acute and Chronic:CHRONIC HEALTH HAZARD: PROLONGED EXPOSURE ABOVE THE OSHA PERMISSIBLE LIMITS MAY RESULT IN LIVER AND KIDNEY DAMAGE. TRICHLOROETHYLENE HAS BEEN EXTENSIVELY STUDIED FOR CHRONIC EFFECTS IN ANIMALS. WHIL E THERE ARE STUDIES IN WHICH TUMORS WERE INDUCED IN MICE, THERE IS NO EVIDENCE THAT TRICHLOROETHYLENE POSES A CARCINOGENIC RISK TO HUMANS. TRICHLOROETHYLENE IS LISTED IN GROUP 3 BY IARC AND IS NOT LI STED BY NTP. Effects of Overexposure:INHALATION: CAN CAUSE IRRITATION OF THE RESPIRATORY TRACT, DIZZINESS, NAUSEA, HEADACHE, LOSS OF COORDINATION AND EQUILIBRIUM. EYE/SKIN: DISCOMFORT, PAIN AND IRRITATION. INGESTION: IRRITATION OF THE MOUTH AND GI TRACT ALONG WITH OTHER EFFECTS AS LISTED ABOVE FOR INHALATION. Medical Cond Aggravated by Exposure:RESPIRATORY ILLNESS, LIVER AND KIDNEY DISEASES. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. EYE/SKIN: FLUSH EYES AND SKIN WITH PLENTY OF WATER FOR A MINIMUM OF 15 MINS WHILE REMOVING CONTAMINATED CLOTHING AND SHOES BEFORE REUSE OR DISCARD. INGESTION: DRINK LARGE QUANTITIES OF WATER. DO NOT INDUCE VOMITING. DO NOT ATTEMPT TO GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IN ALL CASES, SEEK IMMEDIATE MEDICAL ATTENTION!!! ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=60.C, 140.F Extinguishing Media:CARBON DIOXIDE, WATER FOG AND/OR DRY CHEMICAL Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND, SELF-CONTAINED BREATHING APPARATUS FOR POSSIBLE EXPOSURE TO HYDROGEN CHLORIDE AND TRACES OF PHOSGENE. Unusual Fire/Explosion Hazard:VAPORS CONCENTRATED IN A CONFINED OR POORLY VENTILATED AREA CAN BE IGNITED UPON CONTACT WITH HIGH ENERGY SPARK, FLAME OR HIGH INTENSITY SOURCE OF HEAT. THIS CAN OCCUR AT CONCENTRATIONS RANGING BETWEE N 7.8%-52.0% BY VOLUME. DECOMPOSITION OR BURNING CAN PRODUCE HYDROGEN CHLORIDE OR TRACES OF PHOSGENE. ================== Accidental Release Measures ================== Spill Release Procedures:IMMEDIATELY EVACUATE THE AREA AND PROVIDE MAXIMUM VENTILATION. UNPROTECTED PERONNEL SHOULD BE EVACUATED. WEAR PPE. DIKE AREA TO CONTAIN SPILL. TAKE PRECAUTIONS AS NECESSARY TO PREVENT CONTAMINATIO N OF GROUND AND SURFACE WATERS. RECOVER SPILLED MATERIAL ON ABSORBENT SUCH AS SAWDUST OR VERMICULITE AND SWEEP INTO APPROVED CONTAINERS FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:HANDLE WITH REASONABLE CARE. AVOID BREATHING VAPORS. STORE IN COOL PLACE, USING CLOSED CONTAINERS THAT ARE LABELED IN ACCORDANCE WITH STATE AND FEDERAL REGULATIONS. CONCENTRATED VAPORS OF THIS PROD UCT ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS. Other Precautions:AVOID CONTAMINATION OF WATER SUPPLIES. HANDLING, STORAGE AND USE PROCEDURES MUST BE CAREFULLY MONITORED TO AVOID SPILLS AND/OR LEAKS. ANY SPILL OR LEAK HAS THE POTENTIAL TO CAUSE UNDERGROUND WATER C ONTAMINATION WHICH MAY, IF SUFFICIENTLY SEVERE, RENDER A DRINKING WATER SOURCE UNFIT FOR HUMAN CONSU MPTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED RESPIRATORY EQUIPMENT FOR ORGANIC VAPOR. USE SELF-CONTAINED BREATHING APPARATUS OR FULL FACEPIECE AIRLINE RESPIRATOR WITH AUXILIARY SCBA OPERATED IN THE PRESSURE DEMAND MODE FOR W ORK PERFORMED IN STORAGE VESSELS, POORLY VENTILATED ROOMS, AND OTHER CONFINED AREAS. RESPIRATORY PROTECTION PROGRAMS MUST BE IN ACCORDANCE WITH 29 CFR 1910.134 Ventilation:USE LOCAL EXHAUST OR DILUTION VENTILATION AS APPROPRIATE TO CONTROL EXPOSURE TO BELOW PERMISSIBLE LIMITS. Protective Gloves:USE VITON OR SILVER SHIELD GLOVES TO PROTECT SKIN. Eye Protection:WEAR SPLASHPROOF GOGGLES WHEN HANDLING LIQUIDS AND DURING EMERGENCIES. Other Protective Equipment:BOOTS, APRONS, OR CHEMICAL SUITS SHOULD BE USED WHEN NECESSARY TO PREVENT SKIN CONTACT. PERSONAL PROTECTIVE CLOTHING AND USE OF EQUIPMENT MUST BE IN ACCORDANCE WITH 29 CFR 1910.132 AND 29 CFR 1910.133. Supplemental Safety and Health NOTES TO PHYSICIAN: NEVER ADMINISTER ADRENALINE FOLLOWING TRICHLOROETHYLENE OVER EXPOSURE. INCREASED SENSITIVITY OF THE HEART TO ADRENALINE MAY BE CAUSED BY OVEREXPOSURE TO TRICHLOROETHYLENE. HMIS/N FPA RATING: HEALTH=2; FLAMMABILITY=1; REACTIVITY=0 ================== Physical/Chemical Properties ================== Boiling Pt:=90.C, 194.F Melt/Freeze Pt:=-86.4C, -123.5F Vapor Pres:N/E Spec Gravity:1.45 Evaporation Rate & Reference:0.28 (ETHER=1.0) Solubility in Water:NOT MISCIBLE Appearance and Odor:BLUE LIQUID WITH NARCOTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES (CAUSTIC SODA, POTASH), OXIDIZERS Stability Condition to Avoid:AVOID EXTREME HEAT, OPEN FLAME AND WELDING ARCS. =================== Toxicological Information =================== Toxicological Information:INHALATION: SLIGHTLY TOXIC: LCD50 (RAT)=8000 PPM/4 HR; SKIN/EYE IRRITANT: SKIN-MILD IRRITANT=EYE-IRRITANT; INGESTION: MODERATELY TOXIC: LD50 (RAT)=4900-7000 MG/KG PERMISSIBLE EXPOSURE LIMITS: OSHA: 5 0 PPM, 8-HOUR TWA; 200 PPM, 15-MIN STEL; 29 CFR 1910.1000, TABLE 2.2, REVISION 3/1/89. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAMINATED ABSORBENT,SOIL,WATER MUST BE DISPOSED OF IN A PERMITTED HAZARDOUS WASTE MANAGEMENT FACILITY.RECOVERED LIQUIDS MAY BE REUSED, REPROCESSED OR INCINERATED OR MUST BE TREATED IN A PERMITTED H AZARDOUS WASTE MANAGEMENT FACILITY.IT IS YOUR DUTY TO DISPOSE OF THE CHEMICAL MATERIALS AND/OR THEIR CONTAINERS IN ACCORDANCE WITH THE CLEAN AIR ACT =================== MSDS Transport Information =================== Transport Information:DOT: U.S. D.O.T. SHIPPING NAME: TRICHLOROETHYLENE; U.S. D.O.T. HAZARD CLASS: ORM-D ===================== Regulatory Information ===================== SARA Title III Information:INGREDIENT TRICHLOROETHYLENE (80% BY WEIGHT)-A) 311/312 CATEGORIES-ACUTE AND CHRONIC, B) LISTED IN SECTION 313 UNDER TRICHLOROETHYLENE, C) NOT LISTED AS AN EXTREMELY HAZARDOUS SUBSTANCE IN SECTION 302 . Federal Regulatory Information:CERCLA: LISTED IN TABLE 302.4 OF 40 CFR PART 302 AS A HAZARDOUS SUBSTANCE WITH A REPORTABLE QUANTITY OF 1000 POUNDS. RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE RQ MUST BE REPORTED TO THE NATIONA L RESPONSE CENTER. (800) 424-8802. RCRA: WASTE TRICHLOROETHYLENE AND CONTAMINATED SOILS/MATERIALS FROM SPILL CLEANUP AND U228 HAZARDOUS WASTE AS PER 40 CFR 261.33 MUST BE DISPOSED OF ACCORDINGLY UNDE R RCRA. SEE 40 CFR 261.33 AND 261.7 FOR CLEANING REQUIREMENTS OF EMPTY CONTAINERS. TSCA: TRICHLORO ETHYLENE IS ON THE TSCA INVENTORY UNDER CAS # 79-01-6. State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS TRICHLOROETHYLENE, WHICH IS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.