BIRCHWOOD CASEY LABS INC -- ANTIQUE BROWN M38  -- 8010-00N045233
<pre>=====================  Product Identification  =====================

Product ID:ANTIQUE BROWN M38
MSDS Date:07/02/1990
FSC:8010
NIIN:00N045233
=== Responsible Party ===
Company Name:BIRCHWOOD CASEY LABS INC
Address:7900 FULLER RD
City:EDEN PRAIRIE
State:MN
ZIP:55344
Country:US
Info Phone Num:612-937-7940
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:51234
=== Contractor Identification ===
Company Name:BIRCHWOOD CASEY LABS INC
Address:7900 FULLER RD
Box:City:EDEN PRAIRIE
State:MN
ZIP:55344
Country:US
Phone:612-937-7940
CAGE:51234

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 16:COMPLETE, ADJUST PH TO 8.0 W/CALCIUM
    CARBONATE/CALCIUM HYDROXIDE & FILTER. LIQ CAN GO DOWN DRAIN.
RTECS #:9999999ZZ

Ingred Name:NITRIC ACID, COPPER(2+) SALT; (CUPRIC NITRATE)
CAS:3251-23-8
RTECS #:QU7400000
Fraction by Wt: 6%(W/W)
OSHA PEL:1 MG/M3 (CU)
ACGIH TLV:1 MG/M3 (CU)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:PHOSPHORIC ACID
CAS:7664-38-2
RTECS #:TB6300000
Fraction by Wt: 4%(W/W)
OSHA PEL:1 MG/M3;3 STEL
ACGIH TLV:1 MG/M3;3 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:AMMONIUM HYDROGEN FLUORIDE
CAS:1341-49-7
RTECS #:BQ9200000
Fraction by Wt: 1%(W/W)
OSHA PEL:2.5 MG/M3 (F)
ACGIH TLV:2.5 MG/M3 (F)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:TRIDECANOL CONDENSED WITH 6 MOLES ETHYLENE OXIDE;
    (POLYOXYETHYLENE (12) TRIDECYL ALCOHOL)
CAS:24938-91-8
RTECS #:YD4571000
Fraction by Wt: 1%(W/W)
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:WATER. % WT: >85(W/W)
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: SEE ING
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPP DATA:TARGET ORGANS. PRECLUDE FROM CONT W/PROD THOSE
    W/WILSON'S DISEASE/DISEASES OF SKIN, LUNGS, LIVER, (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:KIDNEYS/GI TRACT. SKIN: MAY CAUSE SKIN SENSITIZATION
    RSLTG IN IRRIT, DERM/EDEMA.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: RESP/OXYGEN. IF CONSCIOUS & NOT VOMIT,
    INDUCE EMESIS. SEEK MED ATTN. A DIURETIC WILL SPEED ELIM (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: OF SELENIUM. VITAMIN B COMPLEX, VITAMIN C &
    METHIONINE SUPPLEMENT ARE RECOM. SKIN: REMOVE CONTAMD CLTHG (ING
    11)
RTECS #:9999999ZZ

Ingred Name:ING 10:TO AVOID PRLNGD CONT. WASH AFFECTED AREAS W/SOAP &
    WATER. APPLICATN OF A 10% SODIUM THIOSULFATE CREAM (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: HAS BEEN RECOMMENDED.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: GENERATED FROM TREATING LIQ ARE ASSIGNED
    EPA HAZ WASTE # D010 (EP TOXICITY-SELENIUM). WASTES (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:CAN BE DISPOSED OF THRU A LICENSED WASTE DISP
    COMPANY. TO TREAT LIQ & CONVERT IT TO A SOLID WASTE, ADD 2(ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:OZ OF DEGREASED STEEL WOOL/STEEL MACHINING
    FINES/TURNINGS PER GAL OF DILUTED PROD/8 OZ PER GAL OF CONC.(ING
    16)
RTECS #:9999999ZZ

Ingred Name:ING 15:STIR FREQ/CONTINUOUSLY FOR @ LST 2 HRS. PERIODICALLY
    ADJUST PH DOWN TO 1.5 W/NITRIC ACID. WHEN RXN IS (ING 17)
RTECS #:9999999ZZ

Ingred Name:SELENIOUS ACID
CAS:7783-00-8
RTECS #:VS7175000
Fraction by Wt: 3%(W/W)
OSHA PEL:0.2 MG/M3 (SE)
ACGIH TLV:0.2 MG/M3 (SE)
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT)2.9 G/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: PROD IS AN IRRITANT. IT
    CAN CAUSE RED OF EYES, CONJ, IRITIS, SWELL OF LIDS, A WATERY-MUCOID
    DISCHARGE & CORNEAL OPACITY. INHAL: TOX FUMES NOT GENERATED
    NORMALLY. BRTHG MISTS CAN RSLT IN L OST SENSE OF SMELL, NOSE &
    THROAT IRRIT, GARLIC ODOR OF BRTH, HDCH, DIZZ, LASSITUDE, TREMORS,
    DFCLTY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: BRTHG. TARGET ORGANS: LIVER, KIDNEYS,
    SPLEEN, LUNGS, HEART, ADRENAL GLANDS, PANCREAS. SKIN: PROD IS NOT A
    PRIMARY IRRITANT. HOWEVER, IT CAN PRDCE RED OF SKIN & SLIGHT EDEMA
    ON PRLNGD/RPTD CO NT. ALSO, IT CAN CAUSE SKIN SENSIT IN SOME
    INDIVIDUALS. CHRONIC: EYES: NO DATA SPEC TO CHRONIC EXPOS. INHAL:
    (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYES: IMMED RINSE EYES THORO W/CLEAN WATER FOR @ LST 15 MIN.
    INSTILLATION OF AQUEOUS 10% SODIUM THIOSULFATE SOLN IS ALSO RECOM.
    CONSULT A PHYS. INHAL: REMOVE FROM EXPOS. IF BRTHG DFCLT, PROVIDE
    ARTF R ESP/OXYGEN. CONSULT A PHYS. WASH FOR DELAYED PULM EDEMA.
    DIURETICS SPEED ELIM OF SELENIUM. VITAMIN B COMPLEX, VITAMIN C &
    METHIONINE SUPPLEMENTS RECOMM. INGEST: IF BRTHG DFCLT, PROVIDE ARTF
    (ING 9)

=====================  Fire Fighting Measures  =====================

Flash Point:NON-FLAMMABLE
Extinguishing Media:NON-FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
    .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NON-FLAMMABLE. NON-EXPLOSIVE EXCEPT
    W/WATER- REACTIVE SUBSTANCES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:RECOVER AS MUCH FREE LIQ AS POSSIBLE AND
    COLLECT IN ACID-RESISTANT CONTAINER. USE ABSORBENT TO PICK UP
    RESIDUE. AVOID DISCHARGING THE LIQUID DIRECTLY INTO SEWER/SURF
    WATERS. CERCLA REPORTABLE QTY IS 1	LB FOR SELENIOUS ACID (APPROX
    10 GALL OF PROD).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID CO-LOADING/STORING W/CYANIDES,
    WATER- REACTIVE SUBSTANCES/STRONG REDUCING AGENTS. STORE IN
    ACID-RESIST CONTRS. PROTECT CONTRS FROM PHYSICAL DAM.
Other Precautions:WORKERS HANDLING PRODUCT SHOULD WASH BEFORE SMOKING
    OR EATING.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MSHA APPRVD HIGH EFFICIENCY PARTICULATE
    FILTER RESP, SUPPLIED-AIR RESP/SCBA EACH W/FULL FACEPIECE,
    HELMET/HOOD IF MISTING IS LIKELY.
Ventilation:LOCAL EXHAUST: TO KEEP MISTS BELOW TLV. SPECIAL: EQUIP FOR
    CONTAM & COLLECTION OF MISTS IF SPRAY APPLICATN USED.
Protective Gloves:RUBBER/PLASTIC.
Eye Protection:ANSI APPRVD CHEM (WORK HYGENIC PRAC)
Other Protective Equipment:AS APPROPRIATE TO OPERATION TO GUARD AGAINST
    CONTAMINATION OF CLOTHING AND PROLONGED OR REPEATED SKIN CONTACT.
Work Hygienic Practices:WORKERS HANDLING PRODUCT SHOULD WASH BEFORE
    SMOKING OR EATING. EYE PROT: WORK GOGG W/FULL LNGTH FSHLD .
Supplemental Safety and Health
PH: 1.8(20% V/V SOLN) APPROX 1.2(UNDILUTED). HAZ DECOMP: EVAP TO DRY
    CAN PRDCE SELENIUM DIOXIDE FUMES, OXIDES OF NITROEN & PHOSPHORUS, &
    MEASURABLE LEVELS OF HYDROGEN FLUORIDE. EFTS OF OVEREXP: BESIDE S
    EFTS AS IN ACUTE, CHRONIC EXPOS MAY CAUSE WEAK, PALLOR, ANEMIA
    ENLARGEMENT OF LIVER & DEGENRATIVE CHANGES IN (ING 7)

==================  Physical/Chemical Properties  ==================

HCC:C1
Boiling Pt:B.P. Text:214F,101C
Vapor Density:<1
Spec Gravity:1.055(H2O=1)
pH:SUPDAT
Evaporation Rate &amp; Reference:>1(ETHYL ETHER=1)
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:ODORLESS BLUE LIQUID
Percent Volatiles by Volume:NONE

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
CYANIDES, WATER-REACTIVE SUBSTANCES, ORG SOLV, OILS, STRONG REDUCING
    AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:RXN W/ORG & STRONG REDUCING AGENTS CAN
    PRDCE VOLAT ORGANOSELENIDES/HYDROGEN SELENIDE. THERMAL DECOMP AFTER
    (SUPP DATA)

====================  Disposal Considerations  ====================

Waste Disposal Methods:REVIEW CURRENT LOC, ST & FED; STATUTES, CODES,
    LAWS & REGS TO DETERM CURRENT STATUS & APPROP DISP METH. WASTE
    ANTIQUE BROWN M38/ITS SOLN ARE ASSIGNED EPA HAZ WASTE # D010 (EP
    TOXICITY-SELENIUM) . PREC IPITATES FILTERED FROM OPERATING BATH/
    (ING 13)

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