W R GRACE & CO. DAVISON CHEMICAL DIVISION -- CHROMATOGRAPHIC SILICA GEL -- 6850-01-054-8898
===================== Product Identification ===================== Product ID:CHROMATOGRAPHIC SILICA GEL MSDS Date:01/01/1990 FSC:6850 NIIN:01-054-8898 === Responsible Party === Company Name:W R GRACE & CO. DAVISON CHEMICAL DIVISION Address:10 E BALTIMORE STREET Box:2117 City:BALTIMORE State:MD ZIP:21202-1630 Country:US Info Phone Num:301-659-9000;301-659-9058 Emergency Phone Num:301-659-9000;301-874-2009 CAGE:16210 === Contractor Identification === Company Name:AIR PRODUCTS AND CHEMICALS INC Address:7201 HAMILTON BLVD Box:City:ALLENTOWN State:PA ZIP:18195-1501 Country:US Phone:800-345-3148/ 800-752-1597 CAGE:00742 Company Name:HENDERSON SALES AND SERVICE INC Box:830876 City:RICHARDSON State:TX ZIP:75083 Country:US CAGE:62618 Company Name:SUD-CHEMIE INC/SUB CHEMIE PERFORMANCE PACKAGING DIV Address:926 SOUTH 8TH ST (FORMALLY HUMIDIAL) Box:610 City:COLTON State:CA ZIP:92324-0610 Country:US Phone:909-825-1793 CAGE:00334 Company Name:W R GRACE & CO. DAVISON CHEMICAL DIVISION Address:10 E BALTIMORE STREET Box:2117 City:BALTIMORE State:MD ZIP:21202-1630 Country:US Phone:410-659-9000 CAGE:16210 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL CAS:63231-67-4 RTECS #:VV7322000 OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS >31,600 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SILICA GEL IS A SYNTHETIC AMORPHOUS SILICA (NON-CRYSTALLINE) EPIDEMIOLOGICAL STUDIES INDICATE LOW POTENTIAL FOR ADVERSE HEALTH EFFECTS. DAVISON CONSIDERS SILICA GEL TO BE A NUISANCE DUST. IN ACTIVATED FORM,SILICA GEL ACTS IS DESICCANT & CAN CAUSE DRYING IRRITATION OF MUCOUS MEMBRANES & SKIN IN CASES OF SEVERE EXPOSURE. Explanation of Carcinogenicity:THIS PRODUCT & ITS COMPONENTS ARE NOT LISTED ON THE IARC,NTP OR OSHA CARCINOGEN LISTS. Effects of Overexposure:DRYING OF SKIN & MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:DAVISON KNOWS OF NO MEDICAL CONDITIONS ABNORMALLY AGGRAVATED BY EXPOSURE TO SILICA GEL. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY WASH FROM EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. IF IRRITATION OCCURS AND PERSISTS, SEEK MEDICAL CARE. SKIN:WASH WITH SOAP AND WATER. INGESTED:MATERIAL WILL PASS THROUGH BODY NORMALLY. INHALED: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:NON-FLAMMABLE. USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:MFR GAVE NO INFORMATION ON MSDS. Unusual Fire/Explosion Hazard:MFR GAVE NO INFORMATION ON MSDS. ================== Accidental Release Measures ================== Spill Release Procedures:MFR GAVE NO INFORMATION ON MSDS. Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS. ====================== Handling and Storage ====================== Handling and Storage Precautions:WHEN POURING IN A CONTAINER OF FLAMMABLE LIQUID, GROUND BOTH CONTAINERS ELECRICALLY TO PREVENT STATIC ELECTRIC SPARK. Other Precautions:AVOID PROLONGED BREATHING OF DUST OR CONTACT WITH DUST WITH THE SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DUSTY CONDITIONS PREVAIL, USE OF AN NIOSH/MSHA APPROVED DUST MASK IS RECOMMENDED. Ventilation:MFR GAVE NO INFORMATION ON MSDS. Protective Gloves:SEE OTHER EQUIPMENT Eye Protection:MFR GAVE NO INFORMATION ON MSDS. Other Protective Equipment:WEAR LONG SLEEVES AND CLOSE-WEAVE COTTON GLOVES WITH TIGHT FITTING WRISTLETS. Work Hygienic Practices:MFR:? HMIS:USE GOOD INDUSTRIAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Spec Gravity:2.1 Solubility in Water:INSOLUBLE Appearance and Odor:DRY WHITE GRANULES, FINE SIZED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH HF. Stability Condition to Avoid:MFR GAVE NO INFORMATION ON MSDS. Hazardous Decomposition Products:MFR GAVE NO INFORMATION ON MSDS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT KNOWN TO HAVE ANY ADVERSE EFFECT ON THE AQUATIC INVIRONMENT. IT IS INSOLUBLE AND NON-TOXIC. HMIS:DISPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.