MATHESON TRI-GAS, INC. -- ETHYLENE GLYCOL MONOMETHYL ETHER -- -
===================== Product Identification ===================== Product ID:ETHYLENE GLYCOL MONOMETHYL ETHER MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL MONOMETHYL ETHER CAS:109-86-4 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: irritation, drowsiness, symptoms of drunkenness, kidney damage LONG TERM EXPOSURE: headache, disorientation, sterility, blood disorders, reproductive effects, effects on the brain SKIN CONTACT: SHORT TERM EXPOSURE: same as effects reported in short term inhalation, irritation, symptoms of drunkenness, kidney damage LONG TERM EXPOSURE: same as effects reported in long term inhalation, headache, disorientation, blurred vision, effects on the brain EYE CONTACT: SHORT TERM EXPOSURE: irritation LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: vomiting, digestive disorders, symptoms of drunkenness, kidney damage, coma LONG TERM EXPOSURE: reproductive effects Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For ingestion, consider gastric lavage. Consider oxygen. ===================== Fire Fighting Measures ===================== Flash Point:102 F (39 C) (CC) Autoignition Temp:545 F (285 C) Lower Limits:1.8% Upper Limits:14% Extinguishing Media:alcohol resistant foam, carbon dioxide, regular dry chemical, water, alcohol resistant foam Large fires: Use alcohol-resistant foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Unusual Fire/Explosion Hazard:Moderate fire hazard. Vapor/air mixtures are explosive above flash point. ================== Accidental Release Measures ================== Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. May form peroxides during prolonged storage. Store in a tightly closed container. Avoid contact with light. Store in a cool, dry place. Check peroxide content before use. Do not evaporate or distill to dryness. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 1 ppm Any supplied-air respirator. 2.5 ppm Any supplied-air respirator. 5 ppm Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 100 ppm Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode. 200 ppm Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Escape - Any air-purifying respirator with a full facepiece and an organic vapor canister. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health ETHYLENE GLYCOL MONOMETHYL ETHER: 2-METHOXYETHANOL (EGME): 25 ppm (80 mg/m3) OSHA TWA (skin) 5 ppm ACGIH TWA (skin) 0.1 ppm (0.3 mg/m3) NIOSH recommended TWA 10 hour(s) (skin) ================== Physical/Chemical Properties ================== Boiling Pt:255 F (124 C) Melt/Freeze Pt:-121 F (-85 C) Vapor Pres:9.7 mmHg @ 20 C Vapor Density:2.6 Spec Gravity:0.9647 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:soluble Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:pleasant odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:May form explosive peroxides. Avoid prolonged storage or contact with air, light or storage and use above room temperature. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: oxides of carbon Thermal decomposition products: oxides of carbon Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:ETHYLENE GLYCOL MONOMETHYL ETHER: IRRITATION DATA: 483 mg/24 hour(s) skin-rabbit mild; 97 mg eyes-rabbit; 500 mg/24 hour(s) eyes-rabbit mild; 10 ug eyes-guinea pig mild TOXICITY DATA: 1500 ppm/7 hour(s) inhalation-rat LC50; 1280 mg/kg skin-rabbit LD50; 2370 mg/kg oral-rat LD50 ACUTE TOXICITY LEVEL: Moderately Toxic: inhalation, dermal absorption, ingestion TARGET ORGANS: central nervous system, kidneys MUTAGENIC DATA: Available. REPRODUCTIVE EFFECTS DATA: Available. ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: FISH TOXICITY: 1000000 ug/L 96 hour(s) LC50 (Mortality) Bluegill (Lepomis macrochirus) INVERTEBRATE TOXICITY: 23440 ug/L 48 hour(s) LC50 (Mortality) Mussel (Lamellidens marginalis) ALGAL TOXICITY: >4000 ug/L 72 hour(s) EC50 (Growth) Blue-green algae (Anabaena flosaquae) FATE AND TRANSPORT: BIOCONCENTRATION: 1692 ug/L 4 hour(s) BCF (Residue) Rainbow trout,donaldson trout (Oncorhynchus mykiss) 4.2 ug/L ENVIRONMENTAL SUMMARY: Harmful to aquatic life. ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Ethylene glycol monomethyl ether ID NUMBER: UN1188 HAZARD CLASS OR DIVISION: 3 PACKING GROUP: III LABELING REQUIREMENTS: Flammable liquid ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: Yes FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): 2-METHOXYETHANOL (EGME) Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Known to the state of California to cause the following: 2-METHOXYETHANOL (EGME) Developmental toxicity (Jan 01, 1989) Male reproductive toxicity (Jan 01, 1989) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.