MATHESON TRI-GAS, INC. -- PROPYLENE -- -
===================== Product Identification ===================== Product ID:PROPYLENE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:PROPYLENE CAS:115-07-1 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. EYE CONTACT: Contact with liquid: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: If a large amount is swallowed, get medical attention. NOTE TO PHYSICIAN: For inhalation, consider oxygen. ===================== Fire Fighting Measures ===================== Flash Point:-162 F (-108 C) Autoignition Temp:851 F (455 C) Lower Limits:2.0% Upper Limits:11.1% Extinguishing Media:carbon dioxide, regular dry chemical Large fires: Flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Stop leak if possible without personal risk. Let burn unless leak can be stopped immediately. For smaller tanks or cylinders, extinguish and isolate from other flammables. Evacuation radius: 800 meters (1/2 mile). Stop flow of gas. Unusual Fire/Explosion Hazard:Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Electrostatic discharges may be generated by flow or agitation resulting in ignition or explosion. ================== Accidental Release Measures ================== Spill Release Procedures:Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Keep unnecessary people away, isolate hazard area and deny entry. Remove sources of ignition. Ventilate closed spaces before entering. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.110. Protect from physical damage. Store in a cool, dry place. Store in a well-ventilated area. Avoid heat, flames, sparks and other sources of ignition. Store outside or in a detached building. Grounding and bonding required. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Protective Gloves:Wear insulated gloves. Eye Protection:For the gas: Eye protection not required, but recommended. For the liquid: Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing. Supplemental Safety and Health PROPYLENE: ACGIH (simple asphyxiant) ================== Physical/Chemical Properties ================== Boiling Pt:-53 F (-47 C) Melt/Freeze Pt:-301 F (-185 C) Vapor Pres:7828 mmHg @ 21.1 C Vapor Density:1.5 Spec Gravity:Not applicable pH:Not applicable Evaporation Rate & Reference:Not applicable Solubility in Water:45% Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:Not available Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:May polymerize. May react on contact with air, heat, light or water. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: miscellaneous decomposition products Thermal decomposition products: miscellaneous decomposition products Conditions to Avoid Polymerization:May polymerize. Avoid contact with heat, light, air, water or incompatible materials. Polymerizes with evolution of heat. =================== Toxicological Information =================== Toxicological Information:PROPYLENE: CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal Inadequate Evidence, Group 3; ACGIH: A4 -Not Classifiable as a Human Carcinogen TARGET ORGANS: central nervous system ADDITIONAL DATA: Stimulants such as epinephrine may induce ventricular fibrillation. ===================== Ecological Information ===================== Ecological:FATE AND TRANSPORT: KOW: 229.09 (log = 2.36) (estimated from water solubility) KOC: 539.51 (log = 2.73) (estimated from water solubility) HENRY'S LAW CONSTANT: 9.6 E -4 atm-m3/mol BIOCONCENTRATION: 0.40 (estimated from water solubility) AQUATIC PROCESSES: 1.6829268 hours (River Model: 1 m deep, 1 m/s flow, 3 m/s wind) ENVIRONMENTAL SUMMARY: Relatively non-persistent in the environment. Leaches through the soil or the sediment at a slow rate. Accumulates very little in the bodies of living organisms. Moderately volatile from water. ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Propylene see also Petroleum gases, liquefied ID NUMBER: UN1077 HAZARD CLASS OR DIVISION: 2.1 LABELING REQUIREMENTS: Flammable gas QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: 150 kg ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40 CFR 372.65): PROPYLENE Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.