JLM CHEMICALS CANADA INC -- CYCLOHEXYLAMINE -- 6810-00-805-9798
<pre>===================== Product Identification =====================
Product ID:CYCLOHEXYLAMINE
MSDS Date:10/01/1997
FSC:6810
NIIN:00-805-9798
Status Code:A
=== Responsible Party ===
Company Name:JLM CHEMICALS CANADA INC
Address:701 EVANS AVENUE, SUITE 900
City:TORONTO, ONTARIO H9C 1A3
Country:NA
Info Phone Num:800-567-7455 / 416-449-7750
Emergency Phone Num:416-449-7750
Resp. Party Other MSDS Num.:CODE: 350981
Preparer's Name:REGULATORY AFFAIRS DEPT
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO561
=== Contractor Identification ===
Company Name:JLM CHEMICALS CANADA INC
Address:701 EVANS AVENUE, SUITE 900
Box:City:TORONTO, ONTARIO
Country:NA
Phone:800-567-7455 / 416-449-7750
CAGE:TO561
Company Name:MID-AMERICAN INDUSTRIES
Address:148 TETHERWOOD CT
City:O FALLON
State:IL
ZIP:62269
Country:US
Phone:618-632-3001
Contract Num:SP0450-00-M-D716
CAGE:1NRB8
Company Name:NORTH METAL & CHEMICAL CO (ALIAS, NORTH INDUSTRIAL
CHEMICALS
Address:609 E. KING ST
Box:1904
City:YORK ***2ND PH: 800-966-7848
State:PA
ZIP:17403
Country:US
Phone:PH 717-845-8646 FAX 717-846-7350
CAGE:9A706
============= Composition/Information on Ingredients =============
Ingred Name:CYCLOHEXYLAMINE
CAS:108-91-8
RTECS #:GX0700000
= Wt:99.5
ACGIH TLV:41 MG/M3;10 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 300 MG/KG - TOXIC
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CYCLOHEXYLAMINE IS CORROSIVE TO
BODY TISSUES. CAUSES CHEMICAL BURNS. IT CAN BE SKIN ABSORBED IN
TOXIC AMOUNTS. SKIN CONTACT WITH THE LIQUID OR VAPORS/MISTS MAY
RESULT IN DERMATITIS AND DEEP BU RNS. EYE CONTACT MAY RESULT IN
BURNS AND PERMANENT INJURY. INHALATION OF CYCLOHEXYLAMINE MAY
RESULT IN IRRITATION, LIGHTHEADEDNESS, DROWSINESS, ANXIETY, NAUSEA,
AND VOMITING. CYCLOHEXYLAMINE IS TOXIC BY INGESTION. CHRONIC:
CYCLOHEXLAMINE HAS PRODUCED EMBRYOTOXICITY, LOW BIRTH COUNT,
POST-NATAL MORTALITY, AND DECREASED BODY WEIGHT IN LABORATORY
ANIMALS AT HIGH DOSES.
Explanation of Carcinogenicity:CYCLOHEXLAMINE IS EMBRYOTOXIC, BUT NOT
CARCINOGENIC OR TERATOGENIC. NO EFFECTS HAVE BEEN SEEN IN HUMANS.
Effects of Overexposure:ACUTE: HARMFUL IF SWALLOWED. INHALED OR
ABSORBED THROUGH SKIN, EXTREMELY DESTRUCTIVE TO TISSUE OF THE
MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY RESULT IN SPASM, INFLA MMATION AND EDEMA OF THE
LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE , NAUSEA AND
VOMITING. CHRONIC: THE CHRONIC TOXICOLOGY OF THIS PRODUCT HAS NOT
BEEN FULLY INVESTIGATED. TOXIC BY INHALATION. IN CONTACT WITH SKIN
AND IF SWALLOWED. LABORATORY EXPERIMENTS HAVE SHOWN MU TAGENIC
EFFECTS.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS WITH
WATER. GET IMMEDIATE MEDICAL ATTENTION. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. EYES: IMMEDIATELY WASH EYES WITH RUNNING
WATER FOR 15 M INUTES. GET IMMEDIATE MEDICAL ATTENTION.INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. DILUTE WITH WATER OR MILK AND
GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE
VOMITING IF THE VICT IM IS UNCONSCIOUS OR HAVING CONVULSIONS.
INHALATION: MOVE TO FRESH AIR. AID IN BREATHING, IF NECESSARY, AND
GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:=32.C, 89.6F
Autoignition Temp:=292.C, 557.6F
Lower Limits:NOT AVAILABL
Upper Limits:NOT AVAILABL
Extinguishing Media:SMALL FIRES: CARBON DIOXIDE, DRY CHEMICAL. LARGE
FIRES: ALCOHOL FOAM, WATER SPRAY.
Fire Fighting Procedures:SHUT DOWN MOTORS AND PUMPS TO PREVENT
SPREADING OF FIRE. WEAR FULL PROTECTIVE EQUIPMENT INCLUDING A
SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY CAN BE USED TO
REDUCE INTENSITY OF FLAMES AND TO DIL UTE SPILLS TO NON-FLAMMABLE
MIXTURE, USE WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:NOT PROVIDED
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE SPILL AREA. SHUT OFF ALL IGNITION
SOURCES. AVOID CONTACT WITH EYES, SKIN, CLOTHING. WEAR APPROPRIATE
BREATHING APPARATUS (IF APPLICABLE) PROTECTIVE CLOTHING. DIKE AREA
TO PREVENT SPREADING. P LACE IN CLOSED CONTAINER. USE NON-SPARKING
EQUIPMENT. VENTILATE AREA. ABSORB RESIDUAL MATL WITH SAND, OR
ABSORBENT MATL. WASH SPILL SITE AFTER PICK UP, AVOID RUNOFF OR
RELEASE TO SEWER OR WATERWAYS.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS MUST BE GROUNDED. STORE IN
A COOL AREA, AWAY FROM ALL SOURCES OF HEAT AND IGNITION. KEEP
CONTAINER CLOSED WHEN NOT IN USE, OUTSIDE OR DETACHED STORAGE
PREFERRED. SHOULD BE IN STANDARD FLAMM ABLE LIQUID STORAGE TANKS.
AVOID STATIC ELECTRICITY - GROUND CONTAINERS WHEN TRANSFERRING
PRODUCT.
Other Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM HEAT,
ELECTRICAL EQUIPMENT, SPARKS AND FLAME. DO NOT STORE ABOVE 120 DEG
F. EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUPT, PUNCTURE,
WELD ON OR NEAR DRUM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR.
Ventilation:VENTILATION SYSTEM MUST BE DESIGNED VAPOR AND EXPLOSION
PROOF FOR HANDLING SOLVENT VAPORS. USE ONLY IN CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:FACE SHIELD. SPLASH PROOF CHEMICAL GOGGLES.
Other Protective Equipment:A SAFETY SHOWER AND EYE WASH FACILITY SHOULD
BE AVAILABLE. RUBBER SAFETY BOOTS.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
HCC ASSIGNED BASED ON HIERARCHY TABLE. EVEN THOUGH THE DOT HAZARD LABEL
IS CORROSIVE WITH SUBSIDIARY FLAMMABLE, THE GREATER STORAGE HAZARD
IS VIEWED AS FLAMMABLE.
================== Physical/Chemical Properties ==================
HCC:F7
Boiling Pt:=134.C, 273.2F
Vapor Pres:10.@ 22C / 23. @ 37.7C
Vapor Density:3.42
Spec Gravity:0.867
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:NOT AVAILABLE
Appearance and Odor:LIQUID, UNPLEASANT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT, SPARKS AND OPEN FLAME.
CONTACT WITH INCOMPATIBLES.
Hazardous Decomposition Products:OXIDES OF CARBON (CO,CO2). OXIDES OF
NITROGEN. DECOMPOSITION MAY RESULT ON TOXIC VAPORS. CARBON
MONOXIDE, CYANIDES. NITRITES.
=================== Toxicological Information ===================
Toxicological Information:NOT PROVIDED
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL LOCAL, STATE, AND FEDERAL LAWS AND
REGULATIONS REGARDING DISPOSAL, CLEAN-UP, REMOVAL OR DISCHARGE.
EMPTY CONTAINER MUST NOT BE WASHED OUT OR USED FOR OTHER PURPOSES.
=================== MSDS Transport Information ===================
Transport Information:SEE TRANSPORTATION DATA.
===================== Regulatory Information =====================
SARA Title III Information:SARA EHS, TPQ IS 10000 LB
Federal Regulatory Information:CAA TQ IS 15000 LB
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.